{"id":8334,"date":"2024-05-07T15:34:51","date_gmt":"2024-05-07T08:34:51","guid":{"rendered":"http:\/\/www.mtec.or.th\/en\/?p=8334"},"modified":"2024-05-07T15:37:19","modified_gmt":"2024-05-07T08:37:19","slug":"research-award-32816","status":"publish","type":"post","link":"https:\/\/www.mtec.or.th\/en\/research-award-32816\/","title":{"rendered":"\u0e1c\u0e25\u0e07\u0e32\u0e19\u0e27\u0e34\u0e08\u0e31\u0e22\u0e40\u0e2d\u0e47\u0e21\u0e40\u0e17\u0e04\u0e04\u0e27\u0e49\u0e32\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25 Best Poster Presentation Award \u0e43\u0e19\u0e07\u0e32\u0e19 MRS-Thailand 2019"},"content":{"rendered":"\t\t
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\u0e1b\u0e23\u0e30\u0e40\u0e20\u0e17. Best Poster Presentation Award<\/span>
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\u0e2a\u0e32\u0e02\u0e32 : Polymers,Rubber,Bioplastics,colloid and emulsion<\/span>
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Polylactic acid (PLA) is considered as alternative to petroleum-based polymers due to its biodegradability and commercial availability. Despite its high strength, PLA was brittle i.e. possess low toughness, which needs to be improved for its various applications. In this work, thermoplastic elastomer (TPE) was paired with PLA to produce segmented-pie PLA\/TPE bicomponent fibers with aim to enhance the fiber toughness. In fiber spinning, PLA (6100D, MFI 24 g\/10 min) and TPE (VersifyTM 4301, MFI 25 g\/10 min) were melt at 230\uf0b0C and extruded through 24-hole-die of segmented-pie configuration (50\/50 wt. ratio). The PLA and PLA\/TPE fibers were collected as free fall and at take up speeds (S) of 100, 500 and 1,000 m\/min, whereas TPE fibers were collected only at 100 m\/min due to its elasticity. OM observation on PLA\/TPE fiber cross-section showed that PLA and TPE segments were arranged alternately, with curvature interface between them. Such curvature was explained due to difference in melt viscosity between the two constituent polymers, as evidenced by their measured melt viscosities. Results on fiber tensile testing showed enhance in fiber toughness in PLA\/TPE bicomponent fibers (S1000 m\/min) such that its averaged tensile strength and elongation at break were 1.46 gf\/denier and 74.58 percent, respectively, compared to those of PLA fibers (1.0 gf\/denier and 2.93%). Further SEM investigation showed that broken surface of PLA\/TPE fiber specimen were smooth and the segments remained attached, indicating that both PLA and TPE segments in the fibers undertook tension and broke simultaneously. The segmented-pie configuration, where PLA and TPE segments were alternate, enabled load transfer between the two phases. In this study, it was demonstrated that arranging an elastic TPE in segmented-pie configuration could be considered as an alternative approach to enhance toughness of PLA fibers.<\/span><\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t

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<\/div>\n\t\t<\/div>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"

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