{"id":9744,"date":"2024-05-15T16:25:10","date_gmt":"2024-05-15T09:25:10","guid":{"rendered":"http:\/\/www.mtec.or.th\/en\/?p=9744"},"modified":"2024-05-15T16:30:54","modified_gmt":"2024-05-15T09:30:54","slug":"research-award-1246","status":"publish","type":"post","link":"https:\/\/www.mtec.or.th\/en\/research-award-1246\/","title":{"rendered":"Localied Corrosion Inhibition of Aluminum alloys 7075-T6"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"9744\" class=\"elementor elementor-9744\" data-elementor-post-type=\"post\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-3724ef7 elementor-section-full_width elementor-section-height-default elementor-section-height-default\" data-id=\"3724ef7\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-4ed5d3e\" data-id=\"4ed5d3e\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-5939f6e elementor-widget elementor-widget-heading\" data-id=\"5939f6e\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t<h2 class=\"elementor-heading-title elementor-size-default\">Localied Corrosion Inhibition of Aluminum alloys 7075-T6<\/h2>\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-ae2dfe2 elementor-section-full_width elementor-section-height-default elementor-section-height-default\" data-id=\"ae2dfe2\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-251df94\" data-id=\"251df94\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap\">\n\t\t\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-16100f3 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"16100f3\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-33 elementor-top-column elementor-element elementor-element-7f0f3b1\" data-id=\"7f0f3b1\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap\">\n\t\t\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-33 elementor-top-column elementor-element elementor-element-d79fb57\" data-id=\"d79fb57\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-1a18396 elementor-widget elementor-widget-text-editor\" data-id=\"1a18396\" data-element_type=\"widget\" data-e-type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<p style=\"text-align: center;\"><span style=\"font-size: 18pt;\">\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25<\/span><br \/><span style=\"font-size: 18pt;\">\u0e1b\u0e23\u0e30\u0e40\u0e20\u0e17 Poster<\/span><br \/><span style=\"font-size: 18pt;\">\u0e23\u0e30\u0e14\u0e31\u0e1a\u0e0a\u0e32\u0e15\u0e34<\/span><\/p><p><br \/><span style=\"font-size: 14pt;\"><strong>\u0e42\u0e04\u0e23\u0e07\u0e01\u0e32\u0e23\/\u0e1c\u0e25\u0e07\u0e32\u0e19\u0e17\u0e35\u0e48\u0e44\u0e14\u0e49\u0e23\u0e31\u0e1a\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25 :<\/strong> Localized Corrosion Inhibition of Aluminum alloys 7075-T6 by Calsium Sulfate<\/span><br \/><strong><span style=\"font-size: 14pt;\">\u0e19\u0e31\u0e01\u0e27\u0e34\u0e08\u0e31\u0e22\u0e40\u0e08\u0e49\u0e32\u0e02\u0e2d\u0e07\u0e1c\u0e25\u0e07\u0e32\u0e19 :<\/span><\/strong><br \/><span style=\"font-size: 14pt;\">1.\u0e1b\u0e34\u0e15\u0e34\u0e0a\u0e19 \u0e01\u0e25\u0e48\u0e2d\u0e21\u0e08\u0e34\u0e15<\/span><br \/><span style=\"font-size: 14pt;\">\u0e2b\u0e49\u0e2d\u0e07\u0e1b\u0e0f\u0e34\u0e1a\u0e31\u0e15\u0e34\u0e01\u0e32\u0e23\u0e01\u0e32\u0e23\u0e27\u0e34\u0e40\u0e04\u0e23\u0e32\u0e30\u0e2b\u0e4c\u0e04\u0e27\u0e32\u0e21\u0e40\u0e2a\u0e35\u0e22\u0e2b\u0e32\u0e22\u0e02\u0e2d\u0e07\u0e27\u0e31\u0e2a\u0e14\u0e38\u0e41\u0e25\u0e30\u0e40\u0e17\u0e04\u0e42\u0e19\u0e42\u0e25\u0e22\u0e35\u0e1e\u0e37\u0e49\u0e19\u0e1c\u0e34\u0e27<\/span><br \/><span style=\"font-size: 14pt;\">\u0e0a\u0e37\u0e48\u0e2d\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25\u0e41\u0e25\u0e30\u0e40\u0e01\u0e35\u0e22\u0e23\u0e15\u0e34\u0e22\u0e28\u0e17\u0e35\u0e48\u0e44\u0e14\u0e49\u0e23\u0e31\u0e1a: \u0e23\u0e32\u0e07\u0e27\u0e31\u0e25\u0e0a\u0e19\u0e30\u0e40\u0e25\u0e34\u0e28\u0e01\u0e32\u0e23\u0e1b\u0e23\u0e30\u0e01\u0e27\u0e14\u0e01\u0e32\u0e23\u0e19\u0e33\u0e40\u0e2a\u0e19\u0e2d\u0e1a\u0e17\u0e04\u0e27\u0e32\u0e21<\/span><br \/><span style=\"font-size: 14pt;\">\u0e2b\u0e19\u0e48\u0e27\u0e22\u0e07\u0e32\u0e19\u0e17\u0e35\u0e48\u0e43\u0e2b\u0e49\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25\u0e41\u0e25\u0e30\u0e40\u0e01\u0e35\u0e22\u0e23\u0e15\u0e34\u0e22\u0e28: \u0e01\u0e32\u0e23\u0e1b\u0e23\u0e30\u0e0a\u0e38\u0e21\u0e27\u0e34\u0e0a\u0e32\u0e01\u0e32\u0e23\u0e17\u0e32\u0e07\u0e42\u0e25\u0e2b\u0e27\u0e34\u0e17\u0e22\u0e32\u0e41\u0e2b\u0e48\u0e07\u0e1b\u0e23\u0e30\u0e40\u0e17\u0e28\u0e44\u0e17\u0e22 \u0e04\u0e23\u0e31\u0e49\u0e07\u0e17\u0e35\u0e48 9<\/span><br \/><span style=\"font-size: 14pt;\"><strong>\u0e1c\u0e39\u0e49\u0e21\u0e2d\u0e1a :<\/strong> \u0e28.\u0e14\u0e23.\u0e1b\u0e23\u0e30\u0e2a\u0e32\u0e17 \u0e2a\u0e37\u0e1a\u0e04\u0e49\u0e32<\/span><br \/><span style=\"font-size: 14pt;\">\u0e1e\u0e34\u0e18\u0e35\u0e21\u0e2d\u0e1a\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25\u0e41\u0e25\u0e30\u0e40\u0e01\u0e35\u0e22\u0e23\u0e15\u0e34\u0e22\u0e28: \u0e07\u0e32\u0e19 Localized Corrosion Inhibition of Aluminum alloys 7075-T6 by Calsium Sulfate<\/span><br \/><span style=\"font-size: 14pt;\">\u0e2a\u0e16\u0e32\u0e19\u0e17\u0e35\u0e48.\u0e0a\u0e32\u0e42\u0e15\u0e27\u0e4c \u0e40\u0e14\u0e2d \u0e40\u0e02\u0e32\u0e43\u0e2b\u0e0d\u0e48 \u0e19\u0e04\u0e23\u0e23\u0e32\u0e0a\u0e2a\u0e35\u0e21\u0e32 \u0e27\u0e31\u0e19\u0e17\u0e35\u0e48. 27 \u0e1e.\u0e22. 58<\/span><\/p><p><strong><span style=\"font-size: 14pt;\">\u0e17\u0e35\u0e48\u0e21\u0e32\u0e41\u0e25\u0e30\u0e04\u0e27\u0e32\u0e21\u0e2a\u0e33\u0e04\u0e31\u0e0d\u0e02\u0e2d\u0e07\u0e23\u0e32\u0e07\u0e27\u0e31\u0e25\u0e41\u0e25\u0e30\u0e40\u0e01\u0e35\u0e22\u0e23\u0e15\u0e34\u0e22\u0e28<\/span><\/strong><br \/><span style=\"font-size: 14pt;\">\u0e2a\u0e32\u0e02\u0e32\u0e27\u0e34\u0e0a\u0e32\u0e27\u0e34\u0e28\u0e27\u0e01\u0e23\u0e23\u0e21\u0e42\u0e25\u0e2b\u0e01\u0e32\u0e23 \u0e21\u0e2b\u0e32\u0e27\u0e34\u0e17\u0e22\u0e32\u0e25\u0e31\u0e22\u0e40\u0e17\u0e04\u0e42\u0e19\u0e42\u0e25\u0e22\u0e35\u0e2a\u0e38\u0e23\u0e19\u0e32\u0e23\u0e35 \u0e23\u0e48\u0e27\u0e21\u0e01\u0e31\u0e1a\u0e2a\u0e16\u0e32\u0e1a\u0e31\u0e19\u0e27\u0e34\u0e08\u0e31\u0e22\u0e42\u0e25\u0e2b\u0e30\u0e41\u0e25\u0e30\u0e27\u0e31\u0e2a\u0e14\u0e38 \u0e08\u0e38\u0e2c\u0e32\u0e25\u0e07\u0e01\u0e23\u0e13\u0e4c\u0e21\u0e2b\u0e32\u0e27\u0e34\u0e17\u0e22\u0e32\u0e25\u0e31\u0e22 \u0e2a\u0e16\u0e32\u0e1a\u0e31\u0e19\u0e40\u0e2b\u0e25\u0e47\u0e01\u0e41\u0e25\u0e30\u0e40\u0e2b\u0e25\u0e47\u0e01\u0e01\u0e25\u0e49\u0e32\u0e41\u0e2b\u0e48\u0e07\u0e1b\u0e23\u0e30\u0e40\u0e17\u0e28\u0e44\u0e17\u0e22 \u0e28\u0e39\u0e19\u0e22\u0e4c\u0e40\u0e17\u0e04\u0e42\u0e19\u0e42\u0e25\u0e22\u0e35\u0e42\u0e25\u0e2b\u0e30\u0e41\u0e25\u0e30\u0e27\u0e31\u0e2a\u0e14\u0e38\u0e41\u0e2b\u0e48\u0e07\u0e0a\u0e32\u0e15\u0e34 \u0e2a\u0e16\u0e32\u0e1a\u0e31\u0e19\u0e2d\u0e38\u0e14\u0e21\u0e28\u0e36\u0e01\u0e29\u0e32 \u0e2a\u0e21\u0e32\u0e04\u0e21\u0e27\u0e34\u0e0a\u0e32\u0e0a\u0e35\u0e1e\u0e41\u0e25\u0e30\u0e20\u0e32\u0e04\u0e40\u0e2d\u0e01\u0e0a\u0e19 \u0e02\u0e2d\u0e40\u0e0a\u0e34\u0e0d\u0e17\u0e48\u0e32\u0e19\u0e40\u0e02\u0e49\u0e32\u0e23\u0e48\u0e27\u0e21\u0e01\u0e32\u0e23\u0e1b\u0e23\u0e30\u0e0a\u0e38\u0e21\u0e27\u0e34\u0e0a\u0e32\u0e01\u0e32\u0e23\u0e17\u0e32\u0e07 \u0e42\u0e25\u0e2b\u0e27\u0e34\u0e17\u0e22\u0e32\u0e41\u0e2b\u0e48\u0e07\u0e1b\u0e23\u0e30\u0e40\u0e17\u0e28\u0e44\u0e17\u0e22 \u0e04\u0e23\u0e31\u0e49\u0e07\u0e17\u0e35\u0e48 9 (TMETC9) \u0e0b\u0e36\u0e48\u0e07\u0e21\u0e35\u0e01\u0e33\u0e2b\u0e19\u0e14\u0e08\u0e31\u0e14\u0e02\u0e36\u0e49\u0e19\u0e43\u0e19\u0e23\u0e30\u0e2b\u0e27\u0e48\u0e32\u0e07\u0e27\u0e31\u0e19\u0e17\u0e35\u0e48 25-27 \u0e1e\u0e24\u0e28\u0e08\u0e34\u0e01\u0e32\u0e22\u0e19 2558 \u0e13 \u0e42\u0e23\u0e07\u0e41\u0e23\u0e21\u0e0a\u0e32\u0e42\u0e15 \u0e40\u0e14\u0e2d \u0e40\u0e02\u0e32\u0e43\u0e2b\u0e0d\u0e48 \u0e2d\u0e33\u0e40\u0e20\u0e2d\u0e1b\u0e32\u0e01\u0e0a\u0e48\u0e2d\u0e07 \u0e08\u0e31\u0e07\u0e2b\u0e27\u0e31\u0e14\u0e19\u0e04\u0e23\u0e23\u0e32\u0e0a\u0e2a\u0e35\u0e21\u0e32 \u0e20\u0e32\u0e22\u0e43\u0e15\u0e49 Theme \u2018Ab Initio Metallurgy for the Future\u2019 \u0e2b\u0e23\u0e37\u0e2d \u2018\u0e41\u0e23\u0e01\u0e40\u0e23\u0e34\u0e48\u0e21\u0e42\u0e25\u0e2b\u0e01\u0e32\u0e23\u0e27\u0e34\u0e27\u0e31\u0e12\u0e19\u0e32\u0e01\u0e32\u0e23\u0e2a\u0e39\u0e48\u0e2d\u0e19\u0e32\u0e04\u0e15\u2019 \u0e42\u0e14\u0e22\u0e21\u0e35\u0e27\u0e31\u0e15\u0e16\u0e38\u0e1b\u0e23\u0e30\u0e2a\u0e07\u0e04\u0e4c\u0e40\u0e1e\u0e37\u0e48\u0e2d\u0e40\u0e1b\u0e47\u0e19\u0e40\u0e27\u0e17\u0e35\u0e43\u0e19\u0e01\u0e32\u0e23\u0e19\u0e33\u0e40\u0e2a\u0e19\u0e2d\u0e41\u0e25\u0e30\u0e40\u0e1c\u0e22\u0e41\u0e1e\u0e23\u0e48\u0e1c\u0e25\u0e07\u0e32\u0e19\u0e27\u0e34\u0e08\u0e31\u0e22 \u0e41\u0e25\u0e30\u0e41\u0e25\u0e01\u0e40\u0e1b\u0e25\u0e35\u0e48\u0e22\u0e19\u0e2d\u0e07\u0e04\u0e4c\u0e04\u0e27\u0e32\u0e21\u0e23\u0e39\u0e49\u0e17\u0e32\u0e07\u0e14\u0e49\u0e32\u0e19\u0e42\u0e25\u0e2b\u0e27\u0e34\u0e17\u0e22\u0e32\u0e23\u0e30\u0e2b\u0e27\u0e48\u0e32\u0e07\u0e04\u0e13\u0e32\u0e08\u0e32\u0e23\u0e22\u0e4c \u0e19\u0e31\u0e01\u0e27\u0e34\u0e08\u0e31\u0e22 \u0e19\u0e34\u0e2a\u0e34\u0e15\u0e19\u0e31\u0e01\u0e28\u0e36\u0e01\u0e29\u0e32 \u0e02\u0e49\u0e32\u0e23\u0e32\u0e0a\u0e01\u0e32\u0e23\u0e41\u0e25\u0e30\u0e1e\u0e19\u0e31\u0e01\u0e07\u0e32\u0e19\u0e23\u0e31\u0e10\u0e27\u0e34\u0e2a\u0e32\u0e2b\u0e01\u0e34\u0e08 \u0e2a\u0e21\u0e32\u0e04\u0e21\u0e27\u0e34\u0e0a\u0e32\u0e0a\u0e35\u0e1e\u0e1a\u0e38\u0e04\u0e25\u0e32\u0e01\u0e23\u0e08\u0e32\u0e01\u0e20\u0e32\u0e04\u0e40\u0e2d\u0e01\u0e0a\u0e19\u0e23\u0e27\u0e21\u0e16\u0e36\u0e07\u0e1c\u0e39\u0e49\u0e17\u0e35\u0e48\u0e2a\u0e19\u0e43\u0e08\u0e17\u0e31\u0e48\u0e27\u0e44\u0e1b \u0e44\u0e14\u0e49\u0e21\u0e35\u0e42\u0e2d\u0e01\u0e32\u0e2a\u0e1e\u0e1a\u0e1b\u0e30\u0e41\u0e25\u0e01\u0e40\u0e1b\u0e25\u0e35\u0e48\u0e22\u0e19\u0e2d\u0e07\u0e04\u0e4c\u0e04\u0e27\u0e32\u0e21\u0e23\u0e39\u0e49 \u0e1b\u0e23\u0e30\u0e2a\u0e1a\u0e01\u0e32\u0e23\u0e13\u0e4c \u0e07\u0e32\u0e19\u0e27\u0e34\u0e08\u0e31\u0e22 \u0e41\u0e25\u0e30\u0e41\u0e19\u0e27\u0e04\u0e34\u0e14\u0e17\u0e32\u0e07\u0e42\u0e25\u0e2b\u0e27\u0e34\u0e17\u0e22\u0e32\u0e43\u0e2b\u0e21\u0e48 \u0e46 \u0e0b\u0e36\u0e48\u0e07\u0e01\u0e31\u0e19\u0e41\u0e25\u0e30\u0e01\u0e31\u0e19<\/span><\/p><p><strong><span style=\"font-size: 14pt;\">\u0e23\u0e32\u0e22\u0e25\u0e30\u0e40\u0e2d\u0e35\u0e22\u0e14\u0e42\u0e04\u0e23\u0e07\u0e01\u0e32\u0e23<\/span><\/strong><br \/><span style=\"font-size: 14pt;\">Aluminum alloy 7075-T6 is used in aerospace applications due to its high strength to weight ratio, but this material is susceptible to localized corrosion in condensing atmospheric exposure conditions and is usually protected with an anti-corrosion coating system. CaSO4 is sometimes found as an extender component in corrosion inhibition primer pigment system, such as Deft 02GN084, which has been qualified for military use. The role CaSO4 might play in corrosion protection afforded by the coating system has not been addressed thoroughly in the scientific literature. The goal of this study was to isolate and characterize any inhibiting effect of CaSO4 on aluminum alloy 7075-T6 to understand how it might play a role in non-chromate primer coatings. Samples of AA7075-T6 were exposed to chloride solutions with varying pH via static immersion exposure with and without CaSO4 as an inhibitor for times ranging up to 30 days. The solution pH was varied from 3 to 10 and the chloride concentration was fixed at 0.1 M. Pitting corrosion damage was characterized by optical profilometery (OP) to find pit depth and pit area. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS), were used to characterize the extent of corrosion. Surface analysis was carried out by X-ray photoelectron spectroscopy (XPS). Results showed that sulfate suppressed pitting corrosion under acidic conditions. Calcium did not appear to contribute to inhibition in any of the evaluations carried out. EIS results showed an increase in polarization resistance (Rp) in the presence of sulfate. Thermodynamic calculation and XPS data suggest that the protective film formed in the presence of CaSO4 is Al(OH)SO4.<\/span><\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<div class=\"elementor-column elementor-col-33 elementor-top-column elementor-element elementor-element-c4aa0c1\" data-id=\"c4aa0c1\" data-element_type=\"column\" data-e-type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap\">\n\t\t\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-aabbcc3 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"aabbcc3\" data-element_type=\"section\" data-e-type=\"section\">\n\t\t\t\t\t\t\t<div class=\"elementor-background-overlay\"><\/div>\n\t\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-33 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